What did you do this morning?
You probably got up, showered and put on some clothes, perhaps made from cotton or acrylic. You then might have sipped at a coffee whilst eating a slice of toast spread thickly with butter and jam. After that, you might have travelled to work or school, perhaps by car or bus, both fuelled by petrol or diesel. At some point, you sat down, pulled out your phone or computer and started reading this article.
What do these activities have in common? They all involve organic compounds. From the material of your clothes and the food you eat to the fuel for your car and the retina in your eyes, organic compounds are everywhere.
Organic compounds are molecules that are made up of carbon covalently bonded to other atoms, most commonly hydrogen, oxygen, and nitrogen.
There are hundreds of different organic compounds. In fact, thousands - perhaps even millions. They are all based on carbon atoms, covalently bonded to other elements. These are the two fundamental ideas behind organic compounds.
To tell the truth, there is no fixed definition of an organic compound, and some carbon-based molecules are in fact not organic compounds. These include carbonates, cyanides, and carbon dioxide. The reasons behind their exclusion are mostly historic, instead of being based on any defining feature. Structures such as graphite and diamond are also excluded from the group. Because they are made from just one element, they don't count as compounds.
Organic molecules are all based on the element carbon. Making up the backbone of all the organic compounds in the world is a big task, but carbon successfully rises to the occasion. But what makes it so versatile?
Well, carbon has two properties in particular that make it so good at forming molecules and compounds:
Take a look at carbon's electron configuration, shown below.
Carbon's electron configuration. StudySmarter Originals
You can see that carbon has six electrons. Two are found in an inner shell, whilst four are found in its outer shell (also known as its valence shell). These four outer shell electrons make carbon a tetravalent atom. Atoms tend to want to have full outer shells of electrons, and in carbon's case, this means having eight valence electrons. To achieve a full outer shell, the atom needs to form four covalent bonds. It's not fussy about who it bonds with - it is just as happy bonding with oxygen as it is with nitrogen. This means that carbon forms compounds with a range of different elements, and we'll look at examples of organic molecules featuring both oxygen and nitrogen later.
You know that there are other atoms that have four electrons in their outer shell, such as silicon. Why aren't they as versatile and prevalent as carbon?
It's because carbon is a small atom. Its diminutive size means multiple carbon atoms can fit together easily in complicated structures. We say that it is good at catenation - when atoms of the same element join up in long chains.
The combination of small size and tetravalency means the possible arrangements of carbon atoms, covalently bonded both to each other and to other elements, are practically infinite. This is why we have so many different organic compounds.
Organic compounds are joined together using covalent bonds.
A covalent bond is a bond formed by a shared pair of electrons.
Covalent bonds are formed when two atoms each offer up an electron to form a shared pair. The atoms are held together by the electrostatic attraction between their positive nuclei and these negative electrons. This is why most of the elements found in organic compounds are non-metals - they're the ones that can form covalent bonds.
There are a couple of exceptions to this rule - you can find some metals in organic compounds:
In this next section, we're going to look at different types of organic compounds and ways of classifying them. We can do this in different ways.
First, we'll take a look at functional groups.
A species' functional group is the particular group of atoms responsible for its chemical reactions.
The easiest way to distinguish organic compounds is by their functional group. This is the atom or combination of atoms that makes it react in a certain way. Carboxylic acids contain the carboxyl functional group, often written as COOH, whereas amines contain - you guessed it - the amine functional group, or -NH2.
You'll come across the following functional groups when looking at organic compounds.
Family name | Functional group | Prefix/suffix |
Alkane | C-C | -ane |
Alkene | C=C | -ene |
Alkyne | C≡C | -yne |
Alcohol | R-OH | -ol or hydroxy- |
Halogenoalkane | R-X | Varying suffix-ane |
Aldehyde | R-CHO | -al |
Ketone | R-CO-R | -one |
Carboxylic acid | R-COOH | -oic acid |
Ester | R-COO-R | -oate |
Amine | -NH2 | -amine or amino- |
We explore all of these groups in more detail in the article Functional Groups.
Wondering what the prefixes and suffixes are for? We use them to name organic compounds, as you'll find out in IUPAC Nomenclature.
Molecules with the same functional group react in very similar ways. Because of that, we tend to group them together in a homologous series.
A homologous series is a group of organic molecules with the same functional group, but different carbon chain lengths.
A homologous series has some fixed properties.
Organic molecules can also be classified as aliphatic, aromatic, or alicyclic.
Want to find out more about the wonders of benzene? Head over to Aromatic Chemistry, where all will be explained!
A third way of labelling organic compounds is using the terms saturated and unsaturated.
In biology, you'll probably come across four main groups of organic compounds that are fundamental to life. These are carbohydrates, lipids, proteins, and nucleic acids. We won't go into them here - they're much too important for that! However, you can find out more in the articles dedicated to these molecules: Carbohydrates, Lipids, Proteins, and Nucleic Acids.
Now that we know more about the different types of organic compounds, we can have a look at naming them. The practice of naming organic compounds is known as nomenclature. The official nomenclature system was created by the International Union of Pure and Applied Chemistry (IUPAC), which is the system you need to know for your exams.
To name a molecule, you use the following:
For example, take the molecule 2-bromopropane. The root name -prop- tells us that this molecule is based on a propane chain, which is three carbon atoms long. The suffix -ane indicates that it is an alkane, whilst the prefix bromo- lets us know that this molecule has an additional bromine atom, and so is in fact a halogenoalkane. How about the number 2? That shows that the bromine atom is attached to the second carbon atom in the chain.
2-bromopropane. Image credits: commons.wikimedia.org
Nomenclature is a complicated topic, and so we've created a whole article specially dedicated to solving its mysteries. Head over to IUPAC Nomenclature for more.
Let's now focus our attention on ways of representing organic compounds. We do this using chemical formulae. There are a few different types you need to know about. These include:
One formula, two formulae - formula is the singular, and formulae is the plural. Don't get them mixed up!
Let's start with general formulae.
A general formula is a formula that shows the basic ratio of atoms in a compound or molecule. It can be applied to a whole homologous series.
If you want to represent a whole family of compounds with the same functional group, you can use a general formula. They're useful because they can be applied to all the members of a homologous series.
General formulae express the numbers of atoms of each element in a compound in terms of n. For example, all alkanes have the general formula CnH2n+2. The formula tells us that if an alkane has n carbon atoms, it will have 2n+2 hydrogen atoms. This means that once we know the number of carbon atoms in an alkane, we can always find out its number of hydrogen atoms - you double the carbon number and add 2. Of course, we can go backwards as well - subtracting 2 from the number of hydrogens and then halving the result gives you the number of carbons. The general formula works for all of the alkanes in the alkane homologous series, from the very small to the very large.
General formulae are good at representing a whole family of compounds, but they aren't good at specifying an individual compound. We can do this in several ways. The first way of representing a specific compound is by using its molecular formula.
A molecular formula is a formula that shows the actual number of atoms of each element in a compound.
Let's say that we have an alkane with four carbon atoms. From the general formula, we know that it has (2 x 4) + 2 = 10 hydrogen atoms. Its molecular formula is therefore C4H10.
There's a problem when we only rely on molecular formulae to represent molecules: different molecules can have the same molecular formula. You'll see more of this when we look at isomerism later on. A different type of formula we can use is a structural formula.
A structural formula is a shorthand representation of the structure and arrangement of atoms in a molecule, without showing every bond.
When writing structural formulae, we move along the molecule from one end to the other, writing out each carbon and the groups attached to it separately.
Here's an example. Take the molecular formula C3H6O. This could represent multiple different compounds - for example, propanal or propanone. Propanal has the structural formula CH3CH2CHO. This tells us that it has a -CH3 group, bonded to a -CH2- group, bonded to a -CHO group. In contrast, propanone has the structural formula CH3COCH3. This tells us that it has a -CH3 group, bonded to a -CO- group, bonded to a -CH3 group. Do you notice the slight difference?
Structural formulae. StudySmarter Originals
If we want to show all of the bonds in a compound, we use its displayed formula. Displayed formulae often come in handy when drawing reaction mechanisms.
Displayed formulae show every atom and bond in a molecule.
In displayed formulae, we represent bonds using straight lines. A single straight line tells us that we have a single bond, whereas a double straight line tells us we have a double bond. Although they can be a pain to draw out, displayed formulae are useful because they give us important information about a molecule's unique structure, bonding, and arrangement of atoms.
For example, ethanol has the structural formula CH3CH2OH and the following displayed formula:
Displayed formula of ethanol. StudySmarter Originals
In this example, we've drawn all the bonds as if the molecule were flat on the page. However, bonds aren't like that in real life. If we want to show a bond sticking out of the page, we use a wedged line. If we want to show a bond protruding backwards into the page, we use a dashed line. Here's an example using methane.
Drawing 3D chemical molecules. StudySmarter Originals
The final type of formula we'll look at is the skeletal formula.
Skeletal formulae are another type of formula that act as a shorthand representation of a molecule, showing some aspects of its structure and bonding. It omits certain atoms and bonds in order to simplify the diagram.
Drawing displayed formulae over and over again takes a lot of time. This is where skeletal formulae come in handy. They're an easy way of showing a molecule's structure and bonding without drawing every atom and bond. As in displayed formulae, you represent bonds using straight lines. However, you leave out carbon atoms. You represent these missing carbons using the vertices of the lines, assuming that there is a carbon atom at every unlabelled vertex, junction, or end of a line. You also omit carbon-hydrogen bonds. Instead, you assume that each carbon atom forms exactly four covalent bonds, and that any bonds that aren't shown are carbon-hydrogen bonds.
Sound confusing? Let's take a look at an example. We've already seen the displayed formula of ethanol, CH3CH2OH. Here's how it translates into a skeletal formula.
Skeletal formula of ethanol. StudySmarter Originals
We've learnt about types of organic compounds and the different formulae we can use to represent them. Finally, let's look at isomerism.
Isomers are molecules with the same molecular formula, but different arrangements of atoms.
Do you remember how earlier we mentioned that molecular formulae aren't that helpful, as one molecular formula can represent multiple different molecules? Well, this is why. Isomers contain exactly the same number of atoms of each element, but the atoms are arranged differently.
There are two main types of isomerism in chemistry.
Structural isomers are molecules with the same molecular formula but different structural formulae.
Let's revisit propanal and propanone. As we discovered, they both have the same molecular formula: C3H6O. However, they have different structural formulae. Propanal has the structural formula CH3CH2CHO, and propanone has the structural formula CH3COCH3. This makes them structural isomers.
Structural isomerism can be further split into three subtypes:
Position isomerism in propanol. StudySmarter Originals
Another type of isomerism is stereoisomerism. If you thought structural isomers were similar, you better brace yourself - stereoisomers are even more alike!
Stereoisomers have both the same molecular formula and the same structural formula, but different arrangements of atoms in space.
To identify stereoisomers, you need to look at a molecule's displayed formula. Remember, this is a formula that shows every atom and bond. It also shows the arrangement of atoms and bonds; this is where stereoisomers differ.
Once again, there are a couple of subtypes of stereoisomerism:
For more examples of structural and stereoisomerism in action, take a look at Isomerism.
Organic compounds are molecules that are made up of carbon covalently bonded to other atoms, most commonly hydrogen, oxygen, and nitrogen.
Volatile organic compounds, also known as VOCs, are organic compounds that readily turn into a gas at room temperature. They're emitted by certain solids and liquids.
In general, polar organic compounds are soluble in water. These include molecules with hydroxyl, carboxyl, or amine functional groups. However, nonpolar molecules are insoluble in water. These include molecules with long hydrocarbon chains.
Organic compounds have practically infinite uses. We use them as fuels for vehicles, find them in pharmaceuticals and soaps, eat them as food, and use them as structural materials within our body.
In biology, the four main types of organic compound are carbohydrates, lipids, proteins, and nucleic acids.
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